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The graph shows that sodium arsenate (Na 2 HAsO 4 ) and barium nitrate (Ba(NO 3 ) 2 ) have just the behavior we expect: They become more soluble at higher temperatures

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The BCHep derivatives are also compatible with radical chemistry at the bridgehead, with acid 36 yielding bromide 38 via an iridium-catalysed decarboxylative bromination 35 and N -hydroxyphthalimide 39 undergoing a decarboxylative Minisci reaction to provide heterocyclic derivative 40 (ref